Visible crew/equipment: When Rachel tells her date she's going to have to take a rain check and goes back into the apartment, as she opens the door you can see a cameraman standing inside the apartment. (This is only visible in the broadcast version, not DVD or widescreen).
Revealing mistake: In the scene where they are in the coffee shop talking about Rachel's dream about Chandler. Rachel is carrying a coffee pot around then sits down. When she sits she puts her hand under the coffee pot, which would be extremely hot if it were real.
Continuity mistake: Joey is watching Ross from Monica's window and goes searching for the hot girl. The exterior shot crossing the street between buildings is inconsistent with the interior shots, which show them looking at each other across an alley with no visible fire escapes. The exterior shot crosses a street to a building with street-facing fire escapes on every apartment.
Continuity mistake: In the scene where Ross and Carol are talking and Carol says that all he needs is to find a woman who likes men, a woman comes across the room walking in high heels. The shot is wrong because we see her up until she's half the way through the table, and the next shot shows her four steps back.
Continuity mistake: Ross buys the Ultimate Fighting Combo, a large pop and popcorn at the fight, but when he and Monica sit down, they are never seen again. Furthermore, when Monica talks to Pete at the ring, you can see that the Combo was not set on the floor.