Other mistake: There are two mistakes in the scene where Phoebe spots Joey's picture in the laundromat. For one thing, when Phoebe says "Oh, here it is", she is looking in the opposite direction of the picture. Also, when she says this, her mouth doesn't move at all.
Visible crew/equipment: In the scene where Rachel is trying to hide Ross from Paul, when he's about to go into Paul's bedroom after he says "Did you really hear a bear?", look at the window behind Rachel when the shot is on her. You can see a large light reflected in the glass and it moves slightly (not just in conjunction with the camera, it moves before the camera shifts).
Continuity mistake: In the opening scene in Central Perk when Paul (Elizabeth's dad) takes Ross to one side to talk to him you can see the girl in the blue top enters the door twice: first the shot after Paul says "I'm funny like that" and then again after Ross says "I realise it upsets you".