Other mistake: When Emily first walks in wearing her wedding dress, there is a distinctive difference between that dress and the one Monica picked up from the store a few episodes earlier and tried on (yes, more than that she is also wearing a jacket). There is a band of material at the top of the dress when Emily is wearing it that was not there when Monica wore it.
Factual error: Phoebe discovers that one of the babies has wandered away, and finds the baby inside the open drawer. Yeah, no. These babies aren't even walking yet, much less are they able to lift themselves up past the height of their own bodies and launch themselves into a drawer.
Other mistake: When Ross first goes out to play rugby and goes into the scrum, just after Emily talks to the rest of the players, he jumps into the middle of the scrum where the ball should be. Instead, in the next shot, the rugby ball is to the far left of the shot, not in the actual scrum.
Visible crew/equipment: When Phoebe and Rick are sat on the massage table, keep an eye behind Phoebe's head when the camera is on her, particularly after Rick says, "I can always find another masseuse." You can see the shadow of the boom mic moving.
Continuity mistake: In the scene where Joey is showing kids around the museum, there's a little boy who corrects Joey about the existence of the Mastodon. The kid's arm is by his side at the beginning of the scene. When he begins saying, "Isn't the Mastodon from the Pliocene Epoch?" his left arm is suddenly up and his thumb pointing at the Mastodon.
Continuity mistake: In the scene when Phoebe says goodbye to David, you can see Phoebe's long hair on her back. The scene goes back and forth between Phoebe and David or Phoebe and Joey (after David leaves). Each time the amount of hair on Phoebe's back changes. Sometimes it is a thin bit of hair, other times a large chunk (while the rest of her hair is framing her face in front).