Continuity mistake: In the episode 'TOW Phoebe Runs' when Rachel runs into the horse at the end there is a shot of the horse looking round at her, when the shot changes angle to show Rachel picking herself up you can see that the horse is still looking straight ahead.
Factual error: In the one where Joey and Chandler lose baby Ben on a transit city bus, they later have to pick him up at the transit city headquarters. The man working there assumes that one of them is the father. There is no way that a city official would just give away a baby without checking for ID or a birth certificate or proof of fathership of the child.
Continuity mistake: When Chandler and Monica are talking about Chandler's shark obsession, his arms keep changing with each shot. When the shot is from behind (facing Monica) they are on the couch, and when the shot is in front (facing Chandler), his arms are folded in front of him.
Continuity mistake: Chandler comes down to find Monica and sees that she's playing some game and having fun. He makes a sad and dejected face. The scene cuts back to Monica, and then to the exact same shot again of Chandler making the sad and dejected face.
Continuity mistake: After Chandler shouts at everyone because they are complaining about his smoking, there is an awkward silence and we see a shot of Rachel leaning on the sofa with her arms spread. In the next shot she isn't leaning on the sofa anymore.
Continuity mistake: When Monica is in Richard's room she lights candles then realises Richard's home with another woman so blows out the candles but misses one. Next she hides under the duvet waiting for Richard. When he comes in all candles are unlit but she is still under the bed.
Other mistake: In the scene where Rachel is going to take out the trash, Monica tells her the garbage room is the 3rd door on the left. However, when Rachel comes back with the pizza box and Monica leaves for the garbage room, she leaves the apartment and walks towards the right - there are no doors that way, just the stairs.
Continuity mistake: Phoebe knocks over a vase and has to clean it up because "Let's face it; we're at Monica's." When she turns back around and notices one of the babies is missing, the baby on the right (in the striped top) falls over towards the other baby. A split second later when the shot changes the baby is sitting upright again.
Continuity mistake: In the deleted scene on the DVDs Chandler is leaving the security interview with his holdall over his shoulder by the short strap. The camera cuts to outside the room and the holdall is now level with his legs. (Mistakes in Deleted scenes are valid if they are only in that scene which this is.)