Continuity mistake: When Rachel and Monica are discussing whether or not Rachel should meet Ross at the airport she's taking a bottle of red wine out of the refrigerator, but when she places it on the table in the next camera shot the bottle of wine is suddenly a bottle of white wine.
Visible crew/equipment: In the scene where Rachel is trying to hide Ross from Paul, when he's about to go into Paul's bedroom after he says "Did you really hear a bear?", look at the window behind Rachel when the shot is on her. You can see a large light reflected in the glass and it moves slightly (not just in conjunction with the camera, it moves before the camera shifts).
Continuity mistake: When Phoebe enters the coffee house to get Joey's advice on her outfit for Mike's sister's party, it cuts to Joey saying "You look stop-eating hot", and Phoebe's left hand can be seen making a nervous up-down motion in response. But when it cuts back to her, it is her right hand making the motion and her purse is now in her left hand.
Other mistake: When Ross first goes out to play rugby and goes into the scrum, just after Emily talks to the rest of the players, he jumps into the middle of the scrum where the ball should be. Instead, in the next shot, the rugby ball is to the far left of the shot, not in the actual scrum.