Revealing mistake: When Rachel throws Paulo's clothes over the balcony, they land on the corner of the building, yet the balcony isn't near the corner as there are bedrooms between the place where she throws them and the edge of the building. (00:17:15)Dwarf
Plot hole: Chandler and Ross are surprised to notice that Joey has very small feet. It's well beyond suspension of disbelief to think that at the least Chandler (who, apart from being his best friend, has been his roommate for 8 years) has never noticed the size of Joey's feet before. (00:11:20)
Continuity mistake: When Monica is standing in front of Phoebe, asking if the smell from Joey's is bothering her, the shots of Monica from the front show her arms held out in front of her, but when the shot changes her arms are crossed. This happens twice. (00:11:15)
Continuity mistake: When we first see Ross at the museum, the woman he works with is holding a rock. In the first shot, she is holding onto it with her right hand at the bottom and just before the shot changes she turns away from Ross. In the next shot, she is facing Ross again and her right hand has moved on top of the rock. (00:02:05)Dwarf
Factual error: Before Ross goes out to play the second half of the rugby game, Emily gives him some tips on how to hurt the other guys. She singles out one of the guys, saying he doesn't wear a cup. These guys are all English players who love rugby. Rugby players would NEVER wear a cup for rugby is more of a grinding sport than hit and miss. These guys would be crazy to wear a cup.
Continuity mistake: When Charlie tells Ross about the Met, Ross goes sitting next to her, and his hands are empty when he says: 'Joey really knows his art, huh?' When Charlie says: 'Not so much' Ross suddenly holds a book in his hands. Then, when the shot changes, the book is gone again. It keeps (dis)appearing during the scene. (00:20:35)
Other mistake: In the episode with Ross's wedding to Emily, Joey is talking on a cell phone with Phoebe as he walks down the aisle. Joey holds the phone out to Ross saying 'it's Phoebe', and one can clearly see that the phone's screen is completely blank. The phone isn't even turned on. (00:39:20)