Continuity mistake: When Phoebe sits on the swing (when learning to ride her bike), her scarf has one end down her front and the other over her left shoulder. In the next shot, the end is over her right shoulder instead of her left. A couple of shots later, it is switched back again.
Continuity mistake: In the one where Rachel is in the hospital after having Emma she is in the bed feeding Emma and Ross is sitting right beside of her. They are talking about their relationship and what should come. If you will watch each shot as they go to showing Rachel's face then Ross's you can see that Rachel's hair in one shot is in front of her shoulder and the next shot it is behind her shoulder. This happens several times.
Continuity mistake: After Chandler has been playing the Ms Pacman machine all day he claims his hand has seized up and it appears to look like a claw. From then on in that scene, his hand manages to move around fine. It goes in his pocket, and he waves it around like normal, and then when he mentions his hand again at the end of the scene, it appears to have seized and is clawlike again.
Continuity mistake: In the scene with Robin Williams and Billy Crystal, there is a shot of Rachel, and her hair is hanging straight down. The next shot of Rachel is from a different angle and there is a section of hair behind her ear; in the shot after that it is hanging straight again, and is then behind her ears again.