
Springfield Connection - S6-E23
Continuity mistake: Before Marge sees Homer parking violation, if you look at where he is parked over the first handicapped spot there is a car parked in the first non-handicapped spot. A bit before Marge arrests him there is now a non-handicapped spot between the car and Homer's car. (00:14:35 - 00:15:05)

Tree House of Horror V - S6-E6
Continuity mistake: In 'Time and Punishment,' the blue button on the toaster occasionally differs from being at the bottom of the lever to suddenly at the top, visible in the first shots of Homer fixing the toaster and between shots after Homer sits on the pink fish. (00:09:25 - 00:12:45)

Homer Badman - S6-E9
Revealing mistake: In the scene where Marge's coat pocket bursts open, the candy flows onto the floor. However if you look to the right of her some of the candy seems to almost float above the floor. The candy's direction is completely to the right but because of the floor being angled it spreads over one woman who is standing and there is nothing there to support the candy. (00:04:30)

Tree House of Horror V - S6-E6
Continuity mistake: In 'The Shinning,' Homer is chasing his family with an axe. They are hiding behind a curtain, and then they run outside, away from Homer, opening only one of the double doors. In the following overhead shot of them running through the snow, both doors are now open. (00:07:30)

Tree House of Horror V - S6-E6
Continuity mistake: At the end of 'The Shining, ' the family sits in the snow, Homer holding Willie's portable TV. Later, when they're frozen, Homer is holding nothing, although the TV's snow-topped antenna is still there. Additionally, Homer's left shoulder is missing. This is all due to the lack of correct colorization.
Answer: I'm not sure if this is the one you're thinking of, but an episode of "Ray Bradbury Theatre," called "A Sound of Thunder," dealt with a similar matter: a group of hunters travel back in time to hunt dinosaurs, only to find things have changed when they get back because someone stepped on a butterfly.
Xofer