Brother's Little Helper - S11-E2
Audio problem: Homer's mouth is out of sync when he's naming celebrities who use drugs.
Tree House of Horror X - S11-E4
Continuity mistake: In "I Know What You Diddly-Iddly Did", Marge's necklace keeps changing from red to white when the Simpsons are at church, and when they go back home.
Continuity mistake: Just before Lisa's Presidential "refund adjustment" speech she pushes Bart's tape player off the desk and we can hear it smash off screen. Later in the episode when Lisa agrees to legalise it, he starts playing the same player.
Other mistake: In the scene set in the future after Lisa, as the US President, held a conference with some journalists, just before the scene changes they show a black journalist with eyes not drawn among the crowd.
Guess Who's Coming to Criticize Dinner - S11-E3
Other mistake: In the German version, the Italian cook peeved by Homer's comment on lasagna swings the cleaver at him using an Italian word ("Porcodio") which is a rather strong blasphemy, way stronger than any other expression used in original or in other localizations worldwide.
Answer: I'm not sure if this is the one you're thinking of, but an episode of "Ray Bradbury Theatre," called "A Sound of Thunder," dealt with a similar matter: a group of hunters travel back in time to hunt dinosaurs, only to find things have changed when they get back because someone stepped on a butterfly.
Xofer