The One With The Apothecary Table - S6-E11
Visible crew/equipment: After Ross and Rachel cover the table with the sheet, when Phoebe walks in Rachel says they can turn out the lights and watch the movie, and in the next shot we can see the end of the set wall, the soundstage and a crew member's leg.
Answer: The painting doesn't have a name, and if it does it is never mentioned in this episode.