Continuity mistake: In the beginning of the episode Chandler opens the door to the bathroom and Joey is sitting on the toilet. This is the only episode the toilet is positioned there. It is normally behind the door in other episodes.
Continuity mistake: In this episode, they say the reason Kip was phased out was because he dated Monica and they broke up badly. However, in the first season (in the "Dozen Lasagnes" episode) Chandler says Kip left because he got married. (00:13:50)
Continuity mistake: Rachel and Phoebe are in the Central Perk, talking about leaving the group, and a jacket and a handbag are hanging on the arm of the chair behind Rachel, slightly to her left. Between shots it changes from just the jacket, then just the handbag and so on. This continues throughout the scene when Ross comes in and Phoebe leaves. As she gets up you see both again, however Rachel does not move enough to just show one and hide the other. (00:16:00)
Other mistake: When Ross tells Rachel he can't see her anymore, the door to Monica's room is open revealing a completely blank and empty room. (00:09:50)
Continuity mistake: When the group is in the coffee house discussing Kip there is a bag on the table in front of Monica. When Rachel enters she places her bag on top of the bag already sitting there. Toward the end of this scene Rachel's bag then disappears and only the original bag is now sitting there. (00:13:10)
Plot hole: In TOW Ross tells Rachel he cannot see her following a promise to Emily, the rest of the friends go into Monica's bedroom. Joey hauls out a box from under the bed, saying that he's been hiding it there since Ross said the wrong name at the wedding. Surely Monica, with her obsession for keeping the place clean, would have noticed a box under her bed? (00:04:10)
Audio problem: When Rachel and Ross are in Central Perk, Ross says "Well there's this one thing." Then it cuts to a shot of the side of his head where he says "Okay" and it doesn't match his lips.
Answer: The painting doesn't have a name, and if it does it is never mentioned in this episode.