The One With All The Resolutions - S5-E11
Joey: Do you know something?
Rachel: Do you know something?
Joey: I might know something.
Rachel: I might know something too.
Joey: What's the thing you know?
Rachel: Oh no, I can't tell you until you tell me what you know.
Joey: I can't tell you what I know.
Rachel: Well then I can't tell you what I know.
Joey: Okay, fine. [Pause.] You don't know!
Rachel: All right, how about I go over there and I will walk into Chandler's bedroom and I will see that thing that I think that I know is actually the thing that I think that I know!
Joey: [gasps.] YOU KNOW!
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom