Visible crew/equipment: After the Klingon vessel's attack on the Enterprise, while returning fire just as Kirk orders to maintain firing range at 100% dispersal pattern, the set's unfinished wood plank with grey paint drip marks can be seen at the bottom of the screen. Additionally, at the end when Spock goes to stand beside Kirk's chair (also when he walks away) the actor's mark can be seen on the floor by Spock's feet.
Add timeSuper Grover
Factual error: When Kirk/Spock enter/leave the Council Chamber, the doors quietly open unaided (as though there were motion detectors in operation), yet the Organian culture - determined by Spock to be approximately Class D minus on Richter Scale of Cultures - would not have had such technology. A fact overlooked by Kirk and more importantly, Spock.
Continuity mistake: Kirk has a sunburn on his face and chest (it appears to end partway down his chest-most noticeable in the scene shortly after his identity is revealed to the Klingons). First of all, how does one get a sunburn while flying through space (and one that does not match the pattern of the uniform). If one wants to explain it away as being from a recent shore leave or Enterprise tanning bed, the issue still remains that the intensity of the sunburn changes as the episode continues.
Deliberate mistake: When the Klingons post signs for their rules, they're printed in English. The Klingons have their own language, and people on Organia most certainly aren't English speakers. Even if the Universal Translator allows Kirk and Spock to hear in English, it wouldn't change the look of a sign.