Witches and Warlocks are My Favorite Things - S3-E3
Other mistake: The exterior scene when Clara parachutes in is not the real outside we see throughout the show with neighbors including the Kravitz across the street and fewer trees...and no pine forest. Also, it's obvious Marion Lorne, who was about 80 at the time, was sitting on a swing like apparatus being lowered... understandably.
Answer: Larry had been telling Darrin what it means psychologically that Samantha gave the coat away. Larry said giving it away meant she's happy being married but if she liked the coat it means she desires to be single and carefree. So when Darrin sees the coat, he immediately thinks Samantha doesn't want to be married and the fact that she twitched it means (in his mind) she wants to be a single, carefree witch again.
Bishop73