The One With The Boob Job - S9-E16
Revealing mistake: When Phoebe and Mike walk into Central Perk and announce they're moving in together, Chandler, Monica, and Ross, who's wearing a sweatshirt and khakis, are all sitting on the couch, and after Phoebe's comment about loading up the Volvo and wanting to be a soccer mom, it's David Schwimmer's stand-in, wearing a blue button-down shirt and jeans, who is seated beside Chandler.
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom