Other mistake: As the wedding begins, the first bridesmaid, Felicity, walks down the aisle with a man. He is not part of the wedding party but is wearing the same attire as the best men. He is not seen again throughout the wedding. The only two men in the wedding party are Joey and Chandler.
Other mistake: In the episode with Ross's wedding to Emily, Joey is talking on a cell phone with Phoebe as he walks down the aisle. Joey holds the phone out to Ross saying 'it's Phoebe', and one can clearly see that the phone's screen is completely blank. The phone isn't even turned on.
Other mistake: When Emily first walks in wearing her wedding dress, there is a distinctive difference between that dress and the one Monica picked up from the store a few episodes earlier and tried on (yes, more than that she is also wearing a jacket). There is a band of material at the top of the dress when Emily is wearing it that was not there when Monica wore it.