The One Where Ross Is Fine - S10-E2
Audio problem: When Phoebe and Frank Jr. are talking about giving one of the triplets away, Frank makes a very loud noise but his mouth doesn't move. Making a moan this loud requires you to open your mouth. (00:12:50)
The One With Ross's Wedding, part 2 - S4-E24
Audio problem: When the wedding officiant says "take thee, Ross" his lips don't move. (00:20:35)
The One Where Monica Gets a Roommate - S1-E1
Audio problem: The camera cuts briefly to Chandler as the friends are discussing Monica's love life. During this very brief time, you can see Phoebe's mouth moving but there is no audio of her voice, and Monica's voice is heard talking in the background instead. (00:01:10)
The One With The Princess Leia Fantasy - S3-E1
Audio problem: When Monica answers the door and sees her father, she says "Hey Dad, what are you doing here?" but her lips barely move at all.
The One with the Blackout - S1-E7
Audio problem: When Phoebe is counting down to the last candle burning out you can see Joey blowing out the candle, but the sound of his blow is only heard a second later after he sits back. (00:22:50)
The One With The Cake - S10-E4
Audio problem: When Chandler says, "Ironically, that was the Maxim thing", you can tell it's an overdub. The volume and the background noise is different, and we don't see a shot of him speaking these words. (00:11:20)
The One Where Ross Hugs Rachel - S6-E2
Audio problem: In the pre-theme-song scene, with Phoebe and Ross talking outside the coffeehouse, when Phoebe sends Rachel away in the cab for the second time the sound of the tyres screeching starts while the cab is still stationary.