Revealing mistake: When Luke jumps from Jabba's prisoner's skiff over to another skiff, if you watch Lando hanging underneath the prisoner's skiff, you can easily see that he is a matte painting in this shot, because he doesn't move at all.
Revealing mistake: When Jabba's sail barge begins to explode, you can see that one of the floating skiffs is standing on stilts. (00:36:30)
Revealing mistake: The interior matte painting of the hangar on the Rebel ship holding the stolen Imperial shuttle doesn't match the appearance of the hangar from the exterior shot of the Rebel ship. The interior hangar shows an extended platform and four banks of vertical lights bordering the opening and then walls. From the exterior, the hangar appears to have a big light bank near the opening, and then thinner light banks behind it spaced further apart than the interior shot. The exterior shot also doesn't have a platform. (00:50:45 - 00:53:20)
Revealing mistake: In many of the scenes taking place in outer space, if you look closely you can see polygon borders surrounding space vehicles (X-Wings, Star Destroyers, and even the Death Star) indicating the objects being superimposed into the outer space background. [This mistake may only apply to the Blu Ray version.]