Revealing mistake: When Vader throws the lightsaber at Luke and the platform collapses, the point where the platform's columns connect to the ceiling have expanding circles of smoke coming from them as the columns detach from the ceiling, created by the charges used to sever the platform. (01:50:20)Vader47000
Revealing mistake: When 3PO and R2 are being assigned to their droidly duties in Jabba's palace, there is a shot of a poor droid having hot irons branding his feet. The irons are never closer than an inch from the droid's feet, and the steam that allegedly comes from the burning is obviously being shot out of holes in the droid's feet.
Revealing mistake: Right before Luke leaps from the speeder bike to the scout trooper's speeder, there's a shot showing the front of the speeders. Notice the area surrounding the speeders in this shot. During the rest of the speeder bike chase, the speeders pass through this area several times, even though they are not flying in circles. This can be seen, for example, from the sunlight hitting the ground and the tree on the left side with a bush in front of it. Also, one of the shots where this area is seen is the shot before the speeders pass two more scout troopers, but the background has been flipped.
Revealing mistake: When C3PO and R2D2 are picked up in the sand, there is no sand falling off them. Obviously, C3PO's legs and R2D2 where just placed behind some sand (and not in it) or they used blue screen in this shot.
Revealing mistake: At the beginning of the ground battle on Endor, two stormtroopers are knocked to the ground by the Ewoks. In the following shot, one of the troopers has a big crack in the left shoulder of his armour. The crack was obviously not there in the previous shot. (01:34:40)
Revealing mistake: During the speeder bike chase scenes, speeders bikes don't affect any vegetation, even though they're flying near the ground at incredible speed.
Revealing mistake: When Luke leaves the Death Star in an Imperial shuttle, a large girder or something falls right in front of his ship. If you watch closely, you can see it bounce, revealing the miniature. A huge, heavy girder wouldn't have bounced like this.
Revealing mistake: When Luke and Vader enter the Emperor's throne room, in the shot from behind, you can see the stairs through Luke. (01:26:30)
Revealing mistake: When Luke is being fed to the Rancor, in Jabba the Hutt's dungeon, there are black outlines around the beast's legs, from the composite's blue screen special effect. This was edited out in the special edition rerelease.