Sight Unseen - S3-E5
Factual error: When developing a photo it's first put into a developer chemical, which shows the picture up, then a stop, which stops it from developing anymore, then a fix which "sets" the photo. But in the basement, Prue puts the exposed photo into a tray with chemicals in it where it starts to develop, then into a second tray where it develops fully.
Sight Unseen - S3-E5
Factual error: In the scene where the invisible demon is entering Cole's office, the courthouse shown before the elevator is a New York City courthouse, not San Fransisco. It's confirmed by the presence of a NYC Taxi.
Answer: "Hush, Hush, Hush" Paula Cole.