The One With The Boob Job - S9-E16
Revealing mistake: When Phoebe and Mike walk into Central Perk and announce they're moving in together, Chandler, Monica, and Ross, who's wearing a sweatshirt and khakis, are all sitting on the couch, and after Phoebe's comment about loading up the Volvo and wanting to be a soccer mom, it's David Schwimmer's stand-in, wearing a blue button-down shirt and jeans, who is seated beside Chandler.
Answer: The painting doesn't have a name, and if it does it is never mentioned in this episode.