Visible crew/equipment: In the scene where Ross and Joey are explaining phase two of Chandler's break up (going to strip clubs), the camera switches from the girls to Ross and Joey. Behind them is Monica's kitchen window where you can briefly see a reflection of someone passing by (crew member). At first I thought it could have been Chandler, since he was not in the scene, but after a few moments you see that Chandler has been in the bathroom the whole time.
Continuity mistake: In the opening scene Rachel is holding a white felt pen in her hands and gesturing with it while she talks about the soap opera digest magazine. Between shots the pen sometimes has its cap on and then it's off again so you can see the blue tip.
Revealing mistake: In the scene when they confront the stripper at Chandler's office. Ross stars shouting about his grandmothers ring, and as Chandler says "way to be cool, man", you can see Joey ducking behind Ross, covering his mouth with laughter. A brief cut away, then back and he's standing with the others again looking serious.
Audio problem: When Joey is proposing to Rachel and he tells Phoebe to give him the ring back, she says "No!" and pulls her hand away. When she pulls it away, she hits her chest and there's a thump sound that's clearly the sound of her clip on microphone being hit (it's way too audible to be just a thump on her chest).
Revealing mistake: When Monica gets out of her room to show Chandler her sexy clothing, as she opens the room's door, the buildings from across the street move. The scenario was a curtain and the wind that the door made when she opened it on the set made those curtains with the buildings printed in move.
Continuity mistake: When Ross turns on the camera and sits down in front of it, "flirting" with it and drinking wine, what you can see on the little camera screen is very different from when they play the same clip on the TV, in which looks like he was sitting much closer to the camera then he actually was.