Continuity mistake: Right before Ross and Rachel storm in, the girls show Joey how much their waxing stuff hurts. Phoebe starts putting the wax on Joey's inner arm, but then the shot changes and she is spreading in on the outer side. Also she slaps the strip on and the blue tab is hanging down off his arm, but then the shot changes again and it is on his arm with the other end of the strip hanging off the other side.
Revealing mistake: When Monica offers Joey lemonade and he takes off his clothes and is behind the lamp, the tops of his boxer shorts are visible when he says "Were you just gonna give me lemonade?" Broadcasts may crop off this bottom part, DVD doesn't. You can also see his gray boxer shorts through the plant in the previous shot.
Visible crew/equipment: In the opening shot of Phoebe and Chandler in the "nine millionth" jewelry store looking for a ring, at the top of the screen we can see the tip of the boom mic moving in the wideshot. Then just as Chandler looks into the display case and says, "Ugly ring. Ugly ring. Ugly ring," the boom microphone can be seen moving around in the mirror's reflection behind him.
Visible crew/equipment: After Ross and Monica blurt out each other's secrets to their parents, when Jack says, "And we kind of figured about the porch swing," in his closeup we can see the end of the set wall, with the soundstage behind it and many tape marks on the floor.
Factual error: The restaurant refuses to take anyone's orders until they're all seated, which means that the group is sitting, occupying a table, without earning any revenue for the restaurant. There isn't a restaurant in NYC that would have such a policy, since it basically guarantees that a table becomes a revenue vacuum. (It also makes for very unhappy customers, but that doesn't qualify it as a factual error, since some restaurants might be actually stupid enough to not care about their return customers).
Visible crew/equipment: In the scene where Ross and Joey are explaining phase two of Chandler's break up (going to strip clubs), the camera switches from the girls to Ross and Joey. Behind them is Monica's kitchen window where you can briefly see a reflection of someone passing by (crew member). At first I thought it could have been Chandler, since he was not in the scene, but after a few moments you see that Chandler has been in the bathroom the whole time.
Factual error: In season 4 generally, Phoebe has the shortest pregnancy ever. She gets pregnant as the boys win the girls' apartment. In the next episode Ross meets Emily, after 6 weeks he gets engaged to Emily and they then choose to get married 4 weeks later. Phoebe would only be 10-12 weeks pregnant by the time they fly to London, not in her third trimester.
Continuity mistake: In the opening scene Rachel is holding a white felt pen in her hands and gesturing with it while she talks about the soap opera digest magazine. Between shots the pen sometimes has its cap on and then it's off again so you can see the blue tip.