Continuity mistake: In the one where Ross finds out he's having a boy (series 1), just before Rachel lets it slip, she is sitting on the edge of a chair eating a cookie. Watch her dress, it changes back and forth from being undone from the waist up, to only having two buttons open at the top.
Continuity mistake: When Monica comes in and asks Chandler if she can borrow some milk, Chandler is reading a paper that is flat on the bar. In the next shot he is holding it folded, then he lays it on the counter, and suddenly it is in his hands again.
Continuity mistake: In the scene where Ross explains to Phoebe about "Vikrum" the big dark jewel on her necklace switches repeatedly from hanging at the left side of her neck to the middle, then to the right side and again to the left side again between shots.
Continuity mistake: Just after Rachel has tried to whistle and just blew out crumbs, she picks up the fork with her left hand and places it to the left of the cake on the kitchen counter. In the next shot just before Chandler picks up the cake the fork is back on the right side of the cake near her right hand.
Continuity mistake: When Ross and Monica are at the wedding reception talking to the other guests at their table, a lady wearing a red scarf is standing behind them with her back turned. Throughout the scene the red scarf keeps changing position very quickly - in one shot it's slid down one shoulder, then back up in the next and then slid down again. At the end of the scene it's off her back entirely and she has just slung it over her arms.
Continuity mistake: Between season 4 and season 5 some of the furniture in Chandler's and Joey's hotel room is changing. In TOW Ross' Wedding the three big pictures over the beds show dark spiky plants like ferns and palm trees (as can be seen in the scene where Joey shows Chandler the video with Fergie). In this episode these pictures are completely different - they show a red flower, a sunflower and a dark green plant. The two pictures next to the door are now much smaller in bigger frames and the lamp on the night table between the beds which had a white shade in season 4, now has a black shade. The nightstand between the two beds also has a different shape.
Audio problem: The camera cuts briefly to Chandler as the friends are discussing Monica's love life. During this very brief time, you can see Phoebe's mouth moving but there is no audio of her voice, and Monica's voice is heard talking in the background instead.
Continuity mistake: When Rachel returns from her first interview at Ralph Lauren she takes out a bottle of water out of the fridge. In the following shot her hands are empty and there are only Chandler's and Joey's bottles on the table. Rachel's bottle reappears on the table next to Chandler's and Joey's bottles (that are also standing closer together than before) for a moment just when Chandler starts saying "Well, you could have tried not kissing him" and then vanishes again.