Continuity mistake: Joey is watching Ross from Monica's window and goes searching for the hot girl. The exterior shot crossing the street between buildings is inconsistent with the interior shots, which show them looking at each other across an alley with no visible fire escapes. The exterior shot crosses a street to a building with street-facing fire escapes on every apartment.
Other mistake: When Ross is at Monica's party getting Mr. Green's glasses and cigarettes he bumps into Mrs. Green and ends up having to come up with an alibi for the glasses and cigarettes. He then puts the glasses on, puts a cigarette in his mouth and says 'In fact I'm gonna go out into the hallway and fire up this bad boy'. At this point he walks past Rachel but he stops still as if frozen mid-step just before the shot cuts to him walking out into the hallway.
Factual error: Joey and Chandler are supposedly crossing the George Washington Bridge but the exterior background viewed from inside the car is very obviously a repeat reel of another bridge, and their conversation goes on for far too long for the actual crossing. And the cutaway shot after Chandler is kicked out of the car shows an aerial view of the Brooklyn Bridge.
Continuity mistake: In the scene where Ross and Carol are talking and Carol says that all he needs is to find a woman who likes men, a woman comes across the room walking in high heels. The shot is wrong because we see her up until she's half the way through the table, and the next shot shows her four steps back.