Other mistake: In the episode with Ross's wedding to Emily, Joey is talking on a cell phone with Phoebe as he walks down the aisle. Joey holds the phone out to Ross saying 'it's Phoebe', and one can clearly see that the phone's screen is completely blank. The phone isn't even turned on.
Continuity mistake: When Phoebe and Rachel are first talking about the apothecary table, there are two piles of CDs on it. In the side shot you can see that the two CDs on the top of the pile in front of Rachel are overhanging by a few centimetres. A few shots later, however, the top two CDs are overhanging on a different side.
Factual error: When Ross shows Chandler the book, he claims it is in "the biggest library on campus" at NYU, which would be Bobst library on Washington Square Park South. Later, in Central Perk, when Ross tells Rachel and Joey about the people "making babies" in front of his book, Joey says, "Wait a minute. Fifth floor, against that back wall?" Bobst's fifth floor is conference rooms only; there are no stacks on that floor. Joey might have been confused, but Ross should know better, being a professor and having just visited that location.
Continuity mistake: When the group is in the coffee house discussing Kip there is a bag on the table in front of Monica. When Rachel enters she places her bag on top of the bag already sitting there. Toward the end of this scene Rachel's bag then disappears and only the original bag is now sitting there.
Continuity mistake: In the coffee house when Rachel is talking to Ross about trust, a couple comes in behind her and stands at the bar. In the next shot of Rachel they have switched positions; then they are gone, and you never see them walk past Chandler.
Continuity mistake: In Joanna's office, Chandler and Rachel are pulling his pants from one another while he is cuffed to the filing cabinet. Right before Rachel says "What if I clean your bathroom for a month?" she throws the pants onto a chair, but then when Chandler later says "Freedom. I want my freedom. Why won't you hear me?" he opens the door to yell to Sophie and they are both holding the pants again.
Continuity mistake: In the episode 'TOW Phoebe Runs' when Rachel runs into the horse at the end there is a shot of the horse looking round at her, when the shot changes angle to show Rachel picking herself up you can see that the horse is still looking straight ahead.