Silence in the Library (1) - S4-E8
Revealing mistake: When the Doctor notices the unnatural triangular shadow signalling the presence of the Vashta Nerada and points it out to Donna, the shadow appears over Donna when she's standing in front of it, showing that it's a special effect added to the shot afterwards. (00:11:10)
Silence in the Library (1) - S4-E8
Revealing mistake: Also applying to the second episode of the two-parter, "Forest of the Dead": The keyboards on the Library's computer terminals are very obviously standard Apple keyboards - this in an episode set in the 52nd century.
Chosen answer: The Master knows that deep down, he deserves death for the crimes that he's committed throughout his life, and since he regards The Doctor as his arch-foe, he expects it to be at his hands. The fact that The Doctor is still willing to forgive him after everything the Master's put him through hurts him more deeply than death would.
Captain Defenestrator