The Legend of Sleepy Halliwell - S6-E14
Other mistake: In previous episodes it is stated that good witches don't freeze. But after Piper has been decapitated and her head is placed in the manor, one of the students freezes all the kids by tapping into Piper's freezing power. The kids are all good witches so they should not have frozen.
Other mistake: Paige's spell causes Darryl to acquire invulnerability and uncontrollable super strength. When he opens the door of the squad car, he accidentally rips it completely off. When he tries to put the suspect into the back seat, the man flies through the car and barrels out the other side, taking the other door with him. But immediately before this, Darryl high-fives several of his fellow officers, and they are unharmed. They should have been thrown off their feet and suffered multiple fractures in their hands.
The Legend of Sleepy Halliwell - S6-E14
Other mistake: When Phoebe arrives back from her vision quest to find Piper has been kidnapped she tries to sense from the frozen students which one created the headless horseman. As Gideon, Paige, Chris and Phoebe walk into the conservatory you see Zachery blink rather obviously.
Crimes and Witch-Demeanors - S6-E19
Other mistake: At the end, it shows the Charmed Ones orbing out of the trial, but Chris and Leo never leave. Right after the Charmed Ones orb out, Barbas begins discussing his evil plans with Gideon, so wouldn't Leo and Chris find out that Gideon is plotting against them? After they talk, the camera pans out and Chris and Leo are not there. I guess they just forgot to put in the scene where they leave.
Other mistake: During the second attack on Wyatt, when he lets his force field down the top of head is transparent from the special effects.
It's A Bad, Bad, Bad, Bad World (1) - S6-E22
Other mistake: Isn't it amazing that both evil Paige and good Paige have the same exact rocks on their "sides" when they're fighting in the underworld?
It's A Bad, Bad, Bad, Bad World (1) - S6-E22
Other mistake: Phoebe says there's nowhere to park except blocking the neighbor's driveway. We can see in the opening shot that there is no-one parked in front of the manor, and we see spots across the street. There is also enough room to park where she is without blocking the driveway. At the end of the episode, despite not moving it and also saying that she hasn't, it's not blocking the driveway any more. The patrol guy still shoots her. It's not illegal to park there unless it's blocking the driveway.
The Courtship of Wyatt's Father - S6-E16
Other mistake: When the Darklighter shoots Leo in the attic on the Ghost Plane, the arrow goes all the way through him. He wasn't shown to be using anything other than a normal Darklighter Crossbow, and there wasn't any evidence that, since Leo and Piper were still alive, that the physics of the Ghost Plane are any different from the Normal Plane. Yet, in every other instance of someone getting shot with an arrow from a crossbow, it never, ever penetrates the person's body, and always get stuck.
