The One With Phoebe's Birthday Dinner - S9-E5
Factual error: The restaurant refuses to take anyone's orders until they're all seated, which means that the group is sitting, occupying a table, without earning any revenue for the restaurant. There isn't a restaurant in NYC that would have such a policy, since it basically guarantees that a table becomes a revenue vacuum. (It also makes for very unhappy customers, but that doesn't qualify it as a factual error, since some restaurants might be actually stupid enough to not care about their return customers).
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom