Spider-Man

Secret Wars, Chapter 3: Doom - S5-E11

Revealing mistake: After Dr. Doom has stolen the Beyonder's powers, he demonstrates the powers to Ben Grimm in his throne room by teleporting Red Skull, Dr. Octopus and Smythe off the planet. Next he teleports all the heroes to his throne room, and the shot of all the heroes is from two episodes prior when all the heroes were battling the Lizard. This shot of the heroes also includes Ben Grimm in form as the Thing, meaning Ben Grimm was in two places at once. Spider-Man, the Lizard and the rest of the Fantastic 4 were also already prisoners in Doom's castle, which means they were all in two places at once as well.

Phaneron

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Trivia: Madame Web is voiced by Stan Lee's wife Joan. When Madame Web appears before Stan Lee in the series finale, he asks Spider-Man who that exotic lady is. When Spider-Man and Madame Web are talking about Stan Lee in the final scene of the series, Madame Web remarks that she thinks Stan Lee is truly special.

Phaneron

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Answer: I believe it was just a way to try and show the suit is "oily" or reflective. It also helps define the character's features since otherwise, he'd just be a flat black color. It's similar to how the black suit Spidey had blue outlines. (I don't know why they chose a pink/red color... maybe because red is associated with power/fire/war, so it's a more "evil" color?)

TedStixon

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