The Man From U.N.C.L.E. (1964)

Napoleon Solo: My name is Napoleon Solo. I'm an enforcement agent in Section Two here. That's operations and enforcement.
Illya Kuryakin: I am Illya Kuryakin. I am also an enforcement agent. Like my friend Napoleon, I go and I do whatever I am told to by our chief.
Alexander Waverly: Hmm? Oh, yes. Alexander Waverly. Number One in Section One. In charge of this, our New York headquarters. It's from here that I send these young men on their various missions.

Trivia: "The Man From U.N.C.L.E.'s" original working title was "Solo," and its lead character was named for a spy with a minor role in one of Ian Fleming's early Bond novels. U.N.C.L.E. producer Norman Felton had a handshake agreement with Fleming to use the name and to develop "Solo" as a TV spy series. But the Bond film franchise had other ideas, reneged on the agreement on Fleming's behalf, and sued, forcing the title change. Felton prevailed only in retaining the character's name: Napoleon Solo.