Deliberate mistake: To fix the error of the Enterprise firing phasers from the torpedo bay, the Blu-ray version uses footage from "The Best of Both Worlds" to show phasers firing from the dorsal emitter. In doing so, they created a new goof; the planet El Adrel is not visible in the background during these shots.
Revealing mistake: When Picard takes his seat in the Captain's chair after informing Dathon's crew he has been killed, the reflection of an overhead rig of gelled lights can be seen in the blade of Dathon's knife, which Picard is holding, as Picard says the line, "but at least they're not new enemies."
Chosen answer: The uniform does indeed change colour. It may be due to the need for a green screen in part, or perhaps some lighting altering our perception. That being said, it certainly looks green at the start, blue thereafter.
The show has been done in HD now and not sure if they fix this problem.
Dan23