All The Way - S6-E6
Revealing mistake: In one fight scene, Buffy uses a car door to block a kick from a vampire. The window of the car breaks before the kick connects with it. In fact, it breaks while the foot is still in mid-air.
xx:xx:xx
TwotallSpike: You listen to me. [Kneels in front of her.] I've been alive a bit longer than you, and dead a lot longer than that. I've seen things you couldn't imagine, and done things I prefer you didn't. I don't exactly have a reputation for being a thinker. I follow my blood, which doesn't exactly rush in the direction of my brain. So I make a lot of mistakes, a lot of wrong bloody calls. A hundred plus years, and there's only one thing I've ever been sure of: you. [Buffy looks away; he reaches toward her face.] Hey, look at me. I'm not asking you for anything. When I say, "I love you, " it's not because I want you or because I can't have you. It has nothing to do with me. I love what you are, what you do, how you try. I've seen your kindness and your strength. I've seen the best and the worst of you. And I understand with perfect clarity exactly what you are. You're a hell of a woman. You're the one, Buffy.
Buffy: [Quietly.] I don't wanna be the one.
Willow is turned into a ghost. Throughout the entire episode, she can't touch anything (can't turn the pages of a book, etc.), yet towards the end when she and Giles go to Ethan's shop, and she leaves, you can hear that she opened and closed the door, even though she can walk through walls and can't actually touch the door. The curtain moves when she leaves too.
7 mistakes in Beetlejuice you never spotted
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