Question: Where is Q?
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Answer: He doesn't appear in this film. As the film is set at the very start of Bond's career, it wouldn't make sense - the character that would go on to be Q was introduced in Dr. No, and wasn't created with the title of Q until Goldfinger, by which time Bond was well into his Double-0 career. Also, Casino Royale is a film which doesn't rely heavily on gadgets, unlike a lot of other Bond films, meaning that the character would be a little redundant if he appeared.
The Doctor