Revealing mistake: When Leia and Lando are holding off the stormtroopers while Chewbacca and the droids escape into the Millennium Falcon, a stormtrooper comes running through the doorway. You can see the burn mark on his armour before Lando shoots him. When the trooper is shot, another trooper comes running through the door, also with a burn mark on his armour. Then Leia shoots another (or perhaps the same) trooper, and the burn mark is once again there before the trooper is hit (watch in slow motion). (01:44:20)
Revealing mistake: Right before Luke nicks Vader in the shoulder with his lightsabre, Vader cuts through a railing. There's a hole in the railing exactly where Vader apparently cuts it. Also, if you play it in slow motion, Vader's lightsabre never comes into contact with the railing, yet it sparks.
Revealing mistake: In Cloud City, Lando, Leia and Chewbacca are running to the Millennium Falcon, and when then they run into a door after Leia shoots a stormtrooper, a white rubber sole can be seen under one of Chewie's feet. (01:42:40)
Revealing mistake: In the original (not Special Edition): When the AT-ATs are attacking the Hoth base, they do a camera angle from inside Luke's cockpit. As his snowspeeder is passing through the legs of an AT-AT, part of the cockpit becomes translucent and you can slightly see the AT-AT through a metal bar.
Revealing mistake: After C-3PO gets shot, as Chewbacca walks over to the door, his right foot crushes one of the steps on a small set of stairs. (01:19:25)
Revealing mistake: During the escape from Cloud City, watch as C-3PO's head strikes a lamp on the hull of the Millennium Falcon. It bends out of shape.