Other mistake: During the fight between Luke and Darth Vader, when Vader throws his lightsaber at Luke, it is not only Luke's lightsaber from Episodes IV & V instead of his own, it is ignited upside-down, with the blade protruding from the pommel rather than the emitter. (01:50:20)
Revealing mistake: Vader tosses the Emperor and then collapses on some barrels next to the railing. Look at Vader's arm - the one with the severed hand. His arm is bent at the forearm in a way that arms just don't bend. This is because David Prowse's hand was inside an "elongated" arm to simulate it being chopped off. He couldn't keep his wrist straight, giving the appearance of a bent forearm. (01:57:00)
Revealing mistake: When Jabba's sail barge begins to explode, you can see that one of the floating skiffs is standing on stilts. (00:36:30)
Other mistake: DVD and Blu-ray only: in the Battle of Endor, right after the rebel fighter says "there's too many of them." The Millennium Falcon goes into 1/4 of the picture, you can see a black square spot on the right side of the flash frame due to a bad filter usage. Widescreen only. It does not appear in the 4K release even though it wasn't removed.
Answer: Darth: "Obi-Wan once thought as you do. You don't know the power of the dark side. I must obey my master." It's implied that the dark side is intoxicating, once you totally give in to the dark side it has a hold on you, and appeals to morality and rationalization are useless against your lust for its power. (On a symbolic level, the dark side is a metaphor for vice. Darth Vader is an addict and abusive parent. It's actually funny how many scenes still make sense if you replace "the dark side" with "the bottle" or similar).
TonyPH
If we bring the prequels into it, it's one of the criticisms of those films that they only make the question of how much Anakin is a "true believer" more confusing. But it stands to reason that at first Anakin may feel vindicated in his resentment toward the Jedi. Later on, Vader may not feel that as strongly, but by then his anger has turned toward himself for failing to save Padme. He may feel that a man as terrible as he does not deserve to be "rescued" from the dark side, leading to a feedback loop where he only gets further enamored with its power and does more evil things which causes him to hate himself even more, and so it goes.
TonyPH