Plot hole: Columbo is in the Pauley's hotel room trying to figure out how the bottle landed upright next to his body after he was shot. Devlin - the murderer - turns up unannounced and uninvited. How did Devlin explain that he knew where the victim was staying when he was murdered? Media reports might have mentioned the name of the hotel but there is no way they would have included the room number.
Plot hole: Just before Joe Devlin kills Vincent Pauly in the hotel room, he picks up the Full's Irish Dew whisky bottle with his bare hands. The same bottle falls to the floor when Pauly is shot, and Devlin then kicks it over to the body. Devlin didn't wipe the bottle clean at any point, therefore it will be covered in his fingerprints, but this is never mentioned throughout the episode. There's no way the police would overlook such a basic clue.
Answer: Columbo deduces that the first blow must have been to the front of the head, the force causing the victim to fall backwards and hitting the back of his head hard on the ground.
raywest ★