The Riddler's False Notion (2) - S1-E32
Continuity mistake: When the Riddler has a blindfolded Robin out on the window ledge, the position of Robin's blindfold changes between shots, from covering his nose entirely to being just above it.
Directed by: Leslie H. Martinson
Starring: Cesar Romero, Adam West, Burt Ward, Lee Meriwether
The Riddler's False Notion (2) - S1-E32
Continuity mistake: When the Riddler has a blindfolded Robin out on the window ledge, the position of Robin's blindfold changes between shots, from covering his nose entirely to being just above it.

Smack in the Middle (2) - S1-E2
Revealing mistake: While Riddler is with the unconscious guests at the Moldavian exhibit, in the basement of the Moldavian Pavilion the Mole Hill gang blow up the ceiling to create an entry to the exhibit, on the floor above. They lean two tall ladders at the side of the hole and climb up. When Riddler makes for an escape Batman follows him down below, and now we can see long metal brackets bolting the ladders to the floor for safety. (00:20:20 - 00:22:00)
Commissioner Gordon: Great day in the morning.
Trivia: In his appearances as The Joker, Cesar Romero's moustache is visible under his makeup. Romero refused to shave it off, so his makeup had to be applied over it.
Question: Why were three different men used for the villain Mr. Freeze?
Answer: It's wasn't unusual for multiple actors to play one character on this show. The villains on the TV Batman were played by guest stars, not regular cast members. George Sanders, Otto Preminger, and Eli Wallach played the part at various times. They may simply have only wanted to play the part once or twice, or they were later tied up with other projects, making it necessary to cast someone else. Other characters, like Catwoman, were also played by more than one actress.
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