The Penguin's a Jinx (2) - S1-E4
Continuity mistake: When the Penguin goes to Wayne Manor to put Batman and Robin to sleep with the gas from his umbrella, just before he shoots the orange gas at Robin's suit of armor, there's a quick shot of the armor's helmet. The problem is that there's already an orange stain on the face of the helmet from the orange gas that comes out of the tip of the umbrella, even before Penguin shoots any gas. (00:19:15)