Eyewitness - S1-E12
Continuity mistake: When the immortal who's trying to kill Tessa snipes at her in Duncan's car, his shot shatters the passenger-side window. When Duncan tails Tessa and her police escort to the safehouse, the passenger-side window is intact. (00:30:05 - 00:35:50)
Heart of Ice - S1-E3
Continuity mistake: When Mr. Freeze's henchman Johnny gets his legs frozen, an ice "bridge" connects the gap between his feet. A few shots later and the connective ice is gone, making it look like he is wearing boots made of ice. (00:05:45 - 00:07:00)