The One That Could Have Been, part 1 - S6-E15
Revealing mistake: In the opening credits for both parts, fat Monica jumps on the couch and it lifts up on Chandler's end. If you look carefully at Chandler, you can see him holding one end of the couch with his hand and pressing up with his foot. (00:02:10)
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom