Continuity mistake: In the police station, Kim's right arm is handcuffed to the bench as we see the profile/ master shot of her and Rick, but in the next shot, (the medium/front), Kim's right arm is behind her now and not cuffed, as Rick is being cuffed to the bench. A few seconds later, her right arm is again handcuffed to the bench. Kim's right arm is moving around as she talks to Rick and the scene progresses. Her left arm is finally uncuffed when the detective goes to book her. (00:06:20)
Continuity mistake: When Kim hands the phone number to the cop, he takes it in his right hand. As he turns to walk away, its disappeared. (00:23:15)
Answer: According to Jack in season 5, Nina was "deep cover" before the pair ever met, so it's safe to assume she was recruited before she joined CTU. As for what her primary mission was, who knows? Perhaps it was to gather sensitive intel and pass it on to her superiors. Given that she worked for an intelligence agency, it's not a stretch. Or perhaps we may find out in season seven.
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