Revealing mistake: In Jonathan, Warren and Andrew's van, whenever they're watching something on the monitors fed from their security cameras, you can see that the footage is actually pre-recorded due to the fact that the footage is being played through QuickTime media player.
Revealing mistake: During the song-and-dance number "They Got The Mustard Out", if you look closely at the dancers, the man in green to camera right of the second row is horribly out of step with the music, and with the rest of the group. The spell makes everyone dance far better than they naturally would (Tara loses the clumsiness she often displays, for example), so it is a mistake to have someone under the spell dancing so badly.
Revealing mistake: In the opening of the season 6 episode "Two To Go", Willow has gone crazy and is trying to kill the two remaining members of the Trio, so she is pulling the brick wall of the jail apart brick by brick. The problem is that if you look carefully, they are obviously not bricks being pulled away; they look more like plastic or plaster.
Revealing mistake: The entire scene where Buffy is experiencing accelerated time, shadows of trees move in the wind but never actually grow or shrink. Even over short increments of time, the sun can move shadows noticeably, and judging from the speed of the people around her, Buffy is in accelerated time for at least half an hour.
Revealing mistake: As Willow walks through the forest pursuing Warren, just after we first see Warren running, there's a shot of Willow walking into a bit of a clearing. Her shadow crosses a tree on the right (could be caused by the moon), but then a couple of seconds later another shadow is visible on a tree to the left - obviously an artificially lit forest.
Revealing mistake: Right at the beginning of the episode just before we see Warren squirt Jonathan with water, we see Buffy on one of their security cameras. The footage of her is pre-recorded as the progress bar for QuickTime Media Player is visible at the bottom of the screen. The window was moved down to hide this fact, but not far down enough to hide it completely.
Revealing mistake: The knives Giles throws during Buffy's training are a very poor CGI job if you watch it in slow mo. All three knives Giles takes off the wall are identical, with a broad curved blade and a plain black handle. The first one has a transparent blade as it flies toward Buffy, then we hear it bounce off the far wall and it's way out of scale for the distance. The second knife has a diamond-patterned grip instead of a plain one. The third knife conveniently spins in midair for a second so Buffy can kick it out of the way.
Revealing mistake: In "Dead Things," after Buffy and Spike sleep together, when Spike asks, "Are we having a conversation?" and Buffy says, "What? No?" There is a side shot of her. If you look closely at her back (pausing helps), you can just barely see Buffy's skin colored tube top. Trust me, it's there. The time code is 1:22.