Revealing mistake: In the scene in the coffee house, Phoebe is talking to Monica who is drinking a cup of coffee. Towards the end of the scene, the camera is on Phoebe who is smiling & laughing at Monica. In the right hand corner is a side view of 'Monica' however, it is not Courtney Cox in the scene, but a completely different actress. [Widescreen version only, although the "wrong" nose is visible in the original].
Continuity mistake: Monica is sitting in the living room with all her wedding presents, waiting for Chandler to return. She begins to open a large parcel and reveals a brown cardboard box. Then the camera moves to Joey, and when it moves back, the parcel is wrapped up again. This happens about three times.
Continuity mistake: When Phoebe is talking to Ursula's fiance Eric, he is wiping sweat off his face with a napkin. He puts the napkin to his eye and then in the next shot it changes to the other eye without him having enough time to change it. This happens again when at one point he's wiping his eye and then suddenly his forehead.
Continuity mistake: In The One With Monica's Boots, Monica is removing her trainers and replacing them with her boots so it looks as if she was wearing her boots all along. In one shot her left jean leg is tucked into her boots, but when she stands up it is sitting perfectly.
Audio problem: When Joey is proposing to Rachel and he tells Phoebe to give him the ring back, she says "No!" and pulls her hand away. When she pulls it away, she hits her chest and there's a thump sound that's clearly the sound of her clip on microphone being hit (it's way too audible to be just a thump on her chest).