Napoleon Solo: My name is Napoleon Solo. I'm an enforcement agent in Section Two here. That's operations and enforcement.
Illya Kuryakin: I am Illya Kuryakin. I am also an enforcement agent. Like my friend Napoleon, I go and I do whatever I am told to by our chief.
Alexander Waverly: Hmm? Oh, yes. Alexander Waverly. Number One in Section One. In charge of this, our New York headquarters. It's from here that I send these young men on their various missions.
There are a pair of meta-references to Sonny and Cher's guest appearances in this episode. One of the Harrys at Agnes Sue mentions the pair a few moments before Cher makes her first appearance, and when they appear on screen together for the first time, the song playing under the scene is their #1 hit "I Got You Babe". See more...
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Updates: Series 2
Revealing: Every time the villains' deadly gas, "hydro," is mentioned, the word is badly and very obviously dubbed in, and doesn't match what the actors' lips are saying. This occurred because the original name used, "freon," turned out to be an existing (and patented) refrigerant gas, so the name had to be changed to avoid a trademark lawsuit.
Revealing: When Napoleon Solo arrives at the train station, both the name of the newspaper the man in black is holding, and the name on the station sign are backwards. Additionally, as he arrives by train the man in black is on the left side of the shot. After exiting the train, the man in black appears from the right side of the shot.